期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 846, 期 -, 页码 296-304出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2017.07.003
关键词
Palladium; Heterogeneous catalyst; Recycle; Cross-coupling; Reverse phase silica; Hydrogenation
资金
- Basic Science Research Program through the National Research Foundation of Korea (NRF)
- Ministry of Education [2015R1D1A1A09058536]
- Korean Ministry of Education through the BK21-Plus Project of the Hanyang University Graduate Program
Two catalytic systems, consisting of palladium nanoparticles supported by reverse phase amino functionalized silica are utilized as catalysts for Suzuki-Miyaura reaction and hydrogenation in water. The catalysts were developed by modifying silica into bidentate ligands, using either 2-pyridinecarboxaldehyde or 2,2'-bipyridine-4,4'-dicarboxylic acid. The synthesized catalysts showed quantitative reaction yields and recyclability with negligible leaching of Pd nanoparticles. Various characterization techniques including XPS, ICP-MS, SEM, BET, XRD, TEM, H-1-and C-13-NMR are used to verify the efficiency of the catalysts. (C) 2017 Elsevier B.V. All rights reserved.
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