期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 82, 期 11, 页码 5966-5973出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.7b00659
关键词
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资金
- National Natural Science Foundation of China [U1604283, 21472037, 21372066, U1604182, 21402041]
- Plan for Scientific Innovation Talent of Henan Province [164200510008]
- Program for Innovative Research Team in Science and Technology in University of Henan Province [15IRTSTHN003]
A combined palladium- and photoredox-catalyzed monoselective arylation of 6-arylpurine nucleosides has been developed by employing purine as a directing group via the photoredox reaction, and many functional groups are well tolerated in this direct C-H arylation condition. Various of functionalized purines (nucleosides) which are potentially of great importance in medicinal chemistry could be obtained under visible light irradiation at room temperature within 4 h.
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