期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 82, 期 5, 页码 2399-2406出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b02827
关键词
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资金
- Natural Science Foundation of China [21602119, U1504208]
- He'nan Provincial Department of Science and Technology [152300410117]
A highly diastereo- and enantioselective aziridination of N-sulphonyl ketimines with unfunctionalized ketones was reported. In this efficient method, a sequential direct asymmetric Mannich reaction and oxidative C--H amination were involved, which enabled a straightforward route to multisubstituted-fused aziridines in one pot. More importantly, two different products could be selectively obtained in the reaction by adding or removing a metal additive.
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