期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 82, 期 2, 页码 1224-1230出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b02416
关键词
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资金
- National Key Research and Development Program of China [2016YFA0602900]
- National Natural Science Foundation of China [21472051, 21490572]
- Pearl River S&T Nova Program of Guangzhou [201610010160]
A novel strategy for the synthesis of sulfonylated lactones via Ag-catalyzed radical addition/cyclization reaction of 1,6-enynes and sodium sulfinates has been developed. The reaction presents high stereoselectivity under mild conditions with C4 prochiral center construction in one step. The ESR experiments and relevant mechanistic studies indicated that a radical pathway should be involved in this transformation.
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