期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 82, 期 18, 页码 9312-9320出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.7b01122
关键词
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资金
- National Natural Science Foundation of China [21672072, 21420102003]
- China Postdoctoral Science Foundation [2016T90779, 2015M572303]
- Fundamental Research Funds for the Central Universities [2015ZY001, 2015ZM150]
A copper-catalyzed aerobic oxidative reaction between aromatics or heteroaromatics with KSCN is developed by using O-2 as the oxidant. The combination of Cu(OTf)(2), N,N,N',N'-tetramethylethylenediamine (TMEDA) and BF3 center dot Et2O provides an efficient catalytic system, affording substituted thiocyanation products and 2-aminobenzothiazoles in excellent yields. The reaction also possesses a good functional group tolerance for both strong electron-withdrawing and electron-donating groups.
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