期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 82, 期 22, 页码 11909-11914出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.7b01652
关键词
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资金
- Swedish Research Council [2015-04404]
- Swedish Research Council [2015-04404] Funding Source: Swedish Research Council
The first synthesis of unsymmetric diaryliodonium salts directly from iodine and arenes is presented. The methodology provides diaryliodonium salts with the trimethoxyphenyl (TMP) moiety as dummy group. The protocol avoids the customary use of iodoarenes, which can be both expensive and toxic. Excess reagents are not required, and the reactions are performed under mild conditions. O-Arylations with these TMP salts were demonstrated to be highly chemoselective.
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