期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 82, 期 24, 页码 13663-13670出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.7b02409
关键词
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资金
- National Natural Science Foundation of China [21472082]
- Collaborative Innovation Center of Solid-State Lighting and Energy-Saving Electronics
- Jiangsu 333 program
- IKERBASQUE
- Basque Foundation for Science
- Shenzhen Virtual University Park
- Changzhou Jin-Feng-Huang program
The first example of the S(N)2' reaction type of the detrifluoroacetylatively in situ generated tertiary fluoroenolates in the uncatalyzed reactions with Morita-Baylis-Hillman derivatives has been described. The S(N)2' substitution takes place in a highly chemoselective manner as no corresponding S(N)2 products were observed in the reaction mixtures. Due to the excellent stereochemical outcome, the reactions seem to have an apparent synthetic value for the preparation of structurally new fluorinated oxindoles.
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