期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 82, 期 5, 页码 2664-2671出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b03058
关键词
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资金
- Program to Disseminate Tenure Tracking System (MEXT, Japan)
- Astellas Foundation for Research on Metabolic Disorders
The synthesis of alkylated pyrimidines was achieved via benzophenone-mediated photoinduced coupling between saturated heterocycles and sulfonylpyrimidines. The pyrimidine ring was selectively introduced at the nonacidic C(sp(3))-H bond proximal to heteroatoms including oxygen, nitrogen, and sulfur. This is a coupling reaction mediated solely by photoexcited benzophenone, an organic molecule, without the aid of any metallic catalysts or reagents.
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