期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 82, 期 16, 页码 8761-8768出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.7b01497
关键词
-
资金
- National Science Foundation [NSF 21472073, 21532001]
A copper-catalyzed oxidative cyclization procedure has been developed for the production of 2-sulfonated 9H-pyrrolo[1,2-a]indol-9-ones via the direct sulfonylation of N-propargyl-substituted indoles with sulfonylhydrazides and tert-butyl hydroperoxide (TBHP). This novel protocol, which tolerates a broad range of functional groups, offers a simple, efficient, and atom-economical route to a series of fluorazones in good yields under mild conditions.
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