期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 82, 期 4, 页码 2107-2113出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b02893
关键词
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A novel and concise method for the oxidation of unprotected indole derivatives to synthesize 2-indolylbenzoxazinones in the presence of AIBN under open air has been successfully demonstrated. This metal-free reaction is both atom- and step-efficient and is applicable to a broad scope of substrates. This new methodology provides a facile pathway for oxidative C2-C3 bond cleavage and recyclization of 1H-indoles.
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