期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 82, 期 11, 页码 5669-5677出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.7b00488
关键词
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资金
- National Natural Science Foundation of China [U1504206]
An efficient Cu(OTf)(2)-catalyzed Friedel-Crafts alkylation/cyclizaiton sequence of 3-substituted indoles with isatin-derived oxodienes was developed, and a series of structurally complex and diverse pyrrolo[1,2-a]indole spirooxindoles were first obtained in up to 99% yields. This protocol proved to be quite general and was also robust for the synthesis of 9H-pyrrolo[1,2-a]indoles.
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