期刊
ENERGY & ENVIRONMENTAL SCIENCE
卷 12, 期 11, 页码 3356-3369出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ee02268f
关键词
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资金
- German Federal Ministry for Education and Research (BMBF) within the project Materialforschung fur die Energiewende, (BMWi) project EFFCIS [03SF0540, 0324076B]
- Research Council of Lithuania under SAM project [S-MIP-19-5/SV3-1079]
- BMWi project Speedcigs [0324095D]
- HyPerCells graduate school
- Helmholtz Foundation - Helmholtz Energy Materials Foundry (HEMF)
- European Union's Horizon 2020 research and innovation programme under PerTPV project [763977]
The rapid rise of perovskite solar cells (PSCs) is increasingly limited by the available charge-selective contacts. This work introduces two new hole-selective contacts for p-i-n PSCs that outperform all typical p-contacts in versatility, scalability and PSC power-conversion efficiency (PCE). The molecules are based on carbazole bodies with phosphonic acid anchoring groups and can form self-assembled monolayers (SAMs) on various oxides. Besides minimal material consumption and parasitic absorption, the self-assembly process enables conformal coverage of arbitrarily formed oxide surfaces with simple process control. The SAMs are designed to create an energetically aligned interface to the perovskite absorber without non-radiative losses. For three different perovskite compositions, one of which is prepared by co-evaporation, we show dopant-, additive- and interlayer-free PSCs with stabilized PCEs of up to 21.1%. Further, the conformal coverage allows to realize a monolithic CIGSe/perovskite tandem solar cell with as-deposited, rough CIGSe surface and certified efficiency of 23.26% on an active area of 1 cm(2). The simplicity and diverse substrate compatibility of the SAMs might help to further progress perovskite photovoltaics towards a low-cost, widely adopted solar technology.
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