期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 86, 页码 12984-12987出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc05382d
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资金
- Solvay
- F. W. O. Vlaanderen (Research Foundation Flanders)
- KU Leuven
A series of transition metal-based double metal cyanides (DMCs) were studied as catalysts for the synthesis of nitriles via acid-nitrile exchange reaction. The best nitrile yields were obtained with Co-3[Co(CN6)](2) DMC, which proved to be a versatile, stable, reusable and highly active catalyst, exhibiting an activity comparable to that of homogeneous Lewis acid catalysts.
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