期刊
JOURNAL OF NUCLEAR MATERIALS
卷 493, 期 -, 页码 310-321出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jnucmat.2017.06.006
关键词
LBE; Lead molybdates; Equilibration; Phase diagram; Standard molar Gibbs energy
Partial phase diagrams of Pb-Mo-O system have been established at 773 K and 998 K based on phase equilibration studies. Standard molar Gibbs energy of formation of ternary oxides PbMoO4 and Pb2MoO5 were determined by measuring the equilibrium oxygen partial pressures over relevant phase fields using emf cells and are given by the following expressions: Delta(f)G(m)(o) < PbMoO4 > +/- 0.7(kJ mol(-1)) = -1030.1 + 0.3054(T/K) (T: 772 to 1017 K) D-f G(m)(o) < Pb2MoO5 > +/- 0.8(kJ mol(-1)) = -1248.1 + 0.3872(T/K) (T:741 to 1021 K) (C) 2017 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据