期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 17, 期 41, 页码 9135-9139出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ob01916b
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资金
- National Natural Science Foundation of China [21702182, 21873081]
- China Postdoctoral Science Foundation [2018M640546]
- Fundamental Research Funds for the Central Universities [2019QNA3009]
- Zhejiang University
Vinyl cations exhibit remarkable reactivity towards arene C-H functionalizations. This computational study revealed the key mechanistic details of intramolecular C-H vinylation through a vinyl cation intermediate. Based on the reaction mechanism, the effects of substitution, ring strain and tether length on the reactivity of the vinyl cation were elucidated.
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