期刊
GREEN ENERGY & ENVIRONMENT
卷 4, 期 1, 页码 49-55出版社
KEAI PUBLISHING LTD
DOI: 10.1016/j.gee.2018.06.002
关键词
Superacid; Ionic liquids; Hemicellulose; Hydrolysis; Furfural
类别
资金
- National Natural Science Foundations of China [21566011, 31570560]
- Jiangxi Province Sponsored Programs for Distinguished Young Scholars [20162BCB23026]
- Science & Technology Programs of Jiangxi Province Department of Education [GJJ160272]
Novel superacid SO4H-functionalized ionic liquids (SFILs) were designed and prepared in this work. The catalytic activities of SFILs were evaluated in xylan hydrolysis and xylose dehydration to produce furfural. Combined with the results of acid strength of SFILs characterized by solid-state P-31 MAS NMR, it was found that the catalytic performance of SFILs was positively correlated to their acid strength. The superacid SFIL [Ch-SO4H][CF3SO3] displayed the best catalytic performance with more than 80% yield of furfural, and it was also obviously superior to usual SO3H-functionalized acidic ILs, mineral liquid acids, and acidic resin Amberlyst-15 catalysts in catalytic activity under optimized conditions. In addition, the superacid SFIL [Ch-SO4H][CF3SO3] could be easily separated from reaction system and reused at least five times without obvious decrease. (C) 2018, Institute of Process Engineering, Chinese Academy of Sciences. Publishing services by Elsevier B.V. on behalf of KeAi Communications Co., Ltd.
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