期刊
CATALYSIS SCIENCE & TECHNOLOGY
卷 9, 期 21, 页码 6191-6198出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cy01732a
关键词
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资金
- National Natural Science Foundation of China [21832005, 51602179, 51972195, 21972078, U1832145]
- Recruitment Program of Global Experts, China
- Taishan Scholars Foundation of Shandong Province
In this study, we synthesized noble metal-free Co3O4 as a cocatalyst for a modified ZnO nanorod photocatalyst to achieve efficient ethylene degradation under light irradiation. The Co3O4-decorated ZnO nanorods demonstrate photocatalytic activity for ethylene oxidation that is better than that of pure ZnO and even better than that of the noble metal-based RuO2-modified ZnO. Furthermore, Co3O4-modified ZnO exhibits good stability in a six-cycle experiment. Measurement results indicate that the Co3O4 nanoparticles can effectively promote the transfer and inhibit the recombination of photogenerated electrons and holes during the photocatalytic reaction. Therefore, the Co3O4-modified ZnO nanorod photocatalyst displays excellent photocatalytic properties for ethylene degradation and can effectively realize the complete mineralization of ethylene molecules.
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