期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 88, 页码 13231-13234出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc07236e
关键词
-
资金
- NSFC [21602087, 21871112, 21971090]
- NSF of Jiangsu Province [BK20160212]
A new radical-induced dehydrogenative heterocyclization of arylamines with alpha-diazo carbonyls has been established under metal-free oxidative conditions, enabling two-fold C(sp(2))-H bond amination to access a wide range of functionalized 1,2,4-triazine derivatives with generally good yields by combining KI/tert-butyl peroxide (TBHP). The present protocol features wide substrate scope, commercial accessibility, and mild reaction conditions. Mechanistic details of this radical process are rendered by conducting systematic theoretical calculations.
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