期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 88, 页码 13227-13230出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc07144j
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资金
- Leverhulme Trust
- EPSRC [EP/R013012/1, EP/N020669/1, EP/L027151/1]
- BBSRC [BB/N007700/1]
- ERC Starting Grant (BioNet) [757850]
- ERC-2016 Consolidator Grant (CAM-RIG) [726470]
- BBSRC [BB/N007700/1] Funding Source: UKRI
- EPSRC [EP/N020669/1, EP/L027151/1, EP/R013012/1] Funding Source: UKRI
- European Research Council (ERC) [726470] Funding Source: European Research Council (ERC)
Pseudo[2,3]rotaxanes have been successfully fabricated by the complexation of cucurbit[8]uril (CB[8]) macrocycles with extended viologen derivatives. Two design rules enable the incorporation of a third CB[8] onto a recently reported pseudo[2,2]rotaxane. Incorporation of a third macrocycle confines the dimeric stacking of chromophores into specific alignment, leading to effective electron-delocalisation along their long molecular axis.
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