期刊
JOURNAL OF MATERIALS CHEMISTRY C
卷 7, 期 42, 页码 13176-13181出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9tc04765d
关键词
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资金
- NSFC [21661004, 21971091, 21722107]
- Funding Project for Academic/Technical Leaders of Jiangxi Province [20172BCB22021]
- Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program [2017BT01C161]
Through the combined techniques of variable-temperature X-ray structure analysis, dielectric measurement, isotope substitution and molecular dynamics simulation, we investigate a new supramolecular gyroscope (t-BuNH3)(18-crown-6)[ZnBr3(H2O)]. It undergoes an unusual isostructural phase transition, which is different to the non-isostructural one of the chlorine substituted analogue we reported previously. In addition, their solid solutions can be obtained, with a tunable phase transition temperature and the related properties. The comparative analysis of these homologous supramolecular gyroscopes provides in-depth insight for understanding the mechanism of the rarely observed temperature-induced isostructural phase transition as well as modulating the dipole rotation in crystals.
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