期刊
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
卷 17, 期 9, 页码 6765-6770出版社
AMER SCIENTIFIC PUBLISHERS
DOI: 10.1166/jnn.2017.14462
关键词
Low-Temperature Nitrogen Adsorption; Pore Structure; Diffusion Model; Knudsen Number
类别
资金
- State Key Research Development Program of China [2016YFC0600708]
- National Natural Science Foundation of China [51374216]
- Fundamental Research Funds for the Central Universities [2009kz03]
The nanopore structure of five coal samples was analyzed using low-temperature nitrogen adsorption method. Then, the gas desorption experiments were carried out. Combining the experimental results and pore structure characteristics, the rules of gas diffusion in coal seam were further investigated. The results show that the Knudsen number decreases with the gas pressure and increases with temperature. The type of gas diffusion varies between different rank coals. Gas diffusion model in most coals mainly concentrates on transitional diffusion. However, for the highly developed microporous coal samples (anthracite), the diffusion type is closer to the Knudsen diffusion. Whereas, the main diffusion type is Fick diffusion for macroporous coals, such as lignite. With the increase of pressure, the gas diffusion model will undergo Knudsen diffusion, transition diffusion and Fick diffusion state.
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