期刊
JOURNAL OF MOLECULAR AND ENGINEERING MATERIALS
卷 7, 期 1-2, 页码 -出版社
WORLD SCIENTIFIC PUBL CO PTE LTD
DOI: 10.1142/S2251237319500047
关键词
Nickel cobalt sulfide; CNTs; supercapacitor; SEM; BET
资金
- Natural Science Foundation China [61664009, 51771169]
- youth project of applied basic research of Yunnan Science and Technology Department [2015FD001]
- High-End Scientific and Technological Talents Introduction Project ofYunnan Province [2013HA019]
NiCo2S4/CNTs (NCS/CNTs) hybrid nanostructures have been synthesized by a facile one-step solvothermal method with varying content of CNTs. The structure and morphology of the synthesized NCS/CNTs hybrid revealed the formation of platelets anchored on the CNT matrix. When evaluated as electrode materials for supercapacitor, the as-synthesized NCS/CNT-1 hybrid (with 1% of CNT) manifested remarkable specific capacitance of 1690 F g(-1) at the current density of 5 A g(-1). More importantly, an asymmetric supercapacitor (ASC) assembled based on NCS/CNT-1 as positive electrode and carbon nanotube paper (CNP) as a negative electrode delivered high energy density of 58 Wh kg(-1) under power density of 8 kW kg(-1). Furthermore, the ASC device exhibited high cycling stability and 77.7% of initial specific capacitance retention after 7000 charge-discharge cycles at a current density of 8 A g(-1). The large enhancement in the electrochemical performance is attributed to the benefits of the nanostructured architecture, including good mechanical stability, high electrical conductivity as well as buffering for the volume changes during charge-discharge process. These convincing results show that NCS/CNTs hybrid nanostructures are promising electrode materials for high energy density supercapacitors (SCs).
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