期刊
ENERGY STORAGE MATERIALS
卷 23, 期 -, 页码 491-498出版社
ELSEVIER
DOI: 10.1016/j.ensm.2019.04.015
关键词
Hierarchical porous carbon; Meso-micropores structure; Metal-organic framework; Ionogel polymer electrolyte; Flexible solid-state supercapacitor
资金
- National Natural Science Foundation of China [51472177, 51772206, 11474216]
- Science and Technology Support Program of Tianjin [16ZXCLGX00110, 16ZXCLGX00070]
Reasonable options about carbon-based electrode materials and electrolyte play crucial roles in the pursuant path of high-performance supercapacitors. Herein, the synthesis of hierarchical porous honeycomb-like carbon frameworks (HHCF) is reported, which was prepared through pyrolysis of metal-organic framework composite and subsequent activation process. HHCF with a high surface area and hierarchical meso-/micropores, can provide more adsorption sites and facilitate the fast ion transport. The HHCF electrode delivers a high specific capacitance of 361 F g(-1) at a current density of 1 A g(-1) in aqueous electrolyte and retains 182 F g(-1) at 100 A g(-1). Furthermore, the symmetric supercapacitors fabricated in 1-ethyl-3-methylimidazolium tetrafluoroborate (EMIMBF4) electrolyte exhibits great specific capacitance of 174 F g(-1) at 1 A g(-1) and delivers excellent energy density of 74 Wh kg(-1) at a power density of 872 W kg(-1). More importantly, the flexible solid-state supercapacitor device assembled by HHCF electrodes and EMIMBF4/PVDF-HEP polymer gel electrolyte also presents soaring energy density and excellent flexibility performance. Our work may provide new insight in the design of MOF-derived carbon-based supercapacitor with high energy/power density.
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