期刊
JOURNAL OF MOLECULAR STRUCTURE
卷 1134, 期 -, 页码 511-519出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molstruc.2016.12.098
关键词
Ceramics; Nanostructures; Photocatalyst; Chemical synthesis; Electron microscopy
资金
- council of Iran National Science Foundation
- University of Kashan [159271/1579]
In this work, nanocubes of CaSnO3 have been prepared by a simple and green co-precipitation method. In this technique, for preparation of calcium stannate, we have used from a complex structure of calcium as a new precursor and the synthesis of CaSnO3 have beers done in water as a green solvent. Using of complexing precursors were created a congestion in reaction medium. Different conditions have been studied in synthetic approaches and optimized the effect of different parameters on the morphology of product such as precipitation agent (alkaline), pH, temperature, the rate of stirrer, surfactants and the mole ratio of surfactants for preparation product and obtain the best product in terms of quality and morphology. By using of this CaSnO3, two types of azo dyes (acid blue 92 and acid brown 14) have been degraded at presence of ultraviolet light from aqueous solution. Results display that the powder shows appropriate catalytic behavior for degradation of dyes (77% acid brown 14 and 67% acid black 92). Therefore these nano-cube structures have been used as photocatalysts in presence of UV light for degradation of azo dyes. (C) 2016 Elsevier B.V. All rights reserved.
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