期刊
DALTON TRANSACTIONS
卷 48, 期 41, 页码 15567-15576出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9dt01989h
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资金
- Fonds de la Recherche Scientifique - FNRS [J.0091.18]
- UCLouvain
- Erasmus program
- Faculte des Arts et Sciences
- WestGrid
- Compute Canada
We report several new dyads constituted of cationic iridium(iii) photosensitizers and cobalt(iii) catalyst connected via free pendant pyridine on the photosensitizers. These dyads were studied by X-ray crystallography, electrochemistry, absorption and emission spectroscopy as well as theoretical calculations and were shown to efficiently produce H-2 under visible light irradiation. In every case, the dyad outperformed the equivalent system without a pendant pyridine. The dependence between irradiation wavelength and photocatalytic performances was also studied, with H-2 being evolved with turn-over numbers up to 295, 251, 188 and 78 mol(H2) mol(PS)(-1) under blue, green, yellow and red light, respectively.
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