期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 90, 页码 13574-13577出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc07266g
关键词
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资金
- NSERC
- Canada Research Chairs program
Two new NHC-Cu(i)-[kappa(2)-SNS] complexes were synthesized to directly compare the bifunctional catalytic activity of a hard amido vs. a soft thiolate donor. The Cu thiolate complex catalyzed ketone hydroboration but not hydrosilylation, while the Cu amido complex is a high-performing outer-sphere carbonyl reduction catalyst using boranes and silanes.
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