期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 91, 页码 13721-13724出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc06834a
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资金
- National Natural Science Foundation of China [21703116, 51702180]
- Natural Science Foundation of Shandong Province [ZR2016BQ24, ZR2017MB029]
A new porous organic polymer supported rhodium catalyst (Rh/POL-BINAPa&PPh3) has been developed for the hydroformylation of various alkynes to afford the corresponding alpha,beta-unsaturated aldehydes with high chem- and stereoselectivity, excellent catalytic activity and good reusability (10 cycles). The heterogeneous catalyst exhibited more catalytic activity than the comparable homogeneous Rh/BINAPa/PPh3 system.
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