期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 90, 页码 13582-13585出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc07466j
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资金
- National Natural Science Foundation of China (NSFC) [21502037, 21672048]
- Natural Science Foundation of Zhejiang Province (ZJNSF) [LY19B020006]
- Pandeng Plan Foundation of Hangzhou Normal University for Youth Scholars of Materials, Chemistry and Chemical Engineering
An alkenyl C-H allylation by an exo-palladacycle intermediate is demonstrated, employing unactivated (Z)-alkenes and allyl carbonates. With the use of an 8-aminoquinoline (AQ) derived amide as the directing group, the N,N-bidentate-chelation-assisted C-H activation protocol proceeded under mild and oxidant-free conditions with excellent selectivity. The utility of this approach is demonstrated by the preparative scale, selective conversion of inseparable Z/E alkenes and ready removal of the amide auxiliary to provide the corresponding ester.
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