期刊
CATALYSIS SCIENCE & TECHNOLOGY
卷 9, 期 22, 页码 6370-6378出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cy01738k
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资金
- Max Planck Society
- RWTH Aachen University
- Bundesministerium fur Bildung und Forschung as part of the project MANGAN [03SF0508]
- Cluster of Excellence The Fuel Science Center
Manganese(i) complexes bearing triazole ligands are reported as catalysts for the hydrosilylation of carbonyl and carboxyl compounds. The desired reaction proceeds readily at 80 degrees C within 3 hours at catalyst loadings as low as 0.25 to 1 mol%. Hence, good to excellent yields of alcohols could be obtained for a wide range of substrates including ketones, esters, and carboxylic acids illustrating the versatility of the metal/ligand combination.
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