4.7 Article

Intentional hydrolysis to overcome the hydrolysis problem: detection of Ce(iv) by producing oxidase-like nanozymes with F-

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CHEMICAL COMMUNICATIONS
卷 55, 期 89, 页码 13434-13437

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc06167c

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  1. Natural Sciences and Engineering Research Council of Canada (NSERC)
  2. Canada First Research Excellence Fund (CFREF)

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Polyvalent metal ions are susceptible to hydrolysis, making their reproducible detection by sensors and biosensors difficult. We herein turned this disadvantage into an advantage to develop a high selectivity colorimetric method for detecting Ce(iv) by intentionally hydrolyzing it through heating, where subsequent addition of F- recovered the activity, allowing a detection limit of 3.8 mu M Ce(iv).

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