期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 7, 期 45, 页码 25932-25943出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ta09373g
关键词
-
资金
- Australian Research Council (ARC) Linkage Project [DP160102627, DE170100928]
Sodium-ion batteries (SIBs) hold great promise as power sources because of their low cost and decent electrochemical behavior. Nevertheless, the poor rate performance and long-term cycling capability of anode materials in SIBs still impede their practical application in smart grids and electric vehicles. Herein, we design a delicate method to embed WS2 nanosheets into lotus rhizome-like heteroatom-doped carbon nanofibers with abundant hierarchical tubes inside, forming WS2@sulfur and nitrogen-doped carbon nanofibers (WS2@S/N-C). The WS2@S/N-C nanofibers exhibit a large discharge capacity of 381 mA h g(-1) at 100 mA g(-1), excellent rate capacity of 108 mA h g(-1) at 30 A g(-1), and a superior capacity of 175 mA h g(-1) at 5 A g(-1) after 1000 cycles. The excellent performance of WS2@S/N-C is ascribed to the synergistic effects of WS2 nanosheets, contributing to larger interlayer spacing, and the stable lotus rhizome-like S/N-C nanofiber frameworks which alleviate the mechanical stress. Moreover, the WS2@S/N-C electrode shows obvious pseudocapacitive properties at 1 mV s(-1) with a capacitive contribution of 86.5%. In addition, density functional theory calculations further indicate that the WS2@S/N-C electrode is very favorable for Na storage. This novel synthetic strategy is a promising method for synthesizing other electrode materials for rechargeable batteries in the future.
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