期刊
MATERIALS CHEMISTRY FRONTIERS
卷 3, 期 12, 页码 2751-2758出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9qm00624a
关键词
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资金
- National Natural Science Foundation of China [21672015, 21708001]
- National Major Scientific and Technological Special Project for Significant New Drugs Development'' [2017ZX09303013]
- China Postdoctoral Science Foundation [2018M631272]
A simple strategy for the synthesis of fluorescent nitrogen-rich carbon dots (N-dots) is developed through microwave-assisted reaction of 2-azidoimidazole with different hydroxyl compounds. With the increase of hydroxyl groups of the crosslinkers, the emission property of the corresponding N-dots was enhanced. Among them, N-dots with 2-azidoimidazole and glycerol as the starting materials showed high monodispersity, good stability, excellent water solubility and strong fluorescence emission with fluorescence quantum yield up to 27.9%. These N-dots were further employed as an effective chemosensor for Ag+ analysis via the static quenching effect and a good linear range of Ag+ detection was obtained from 20 nM to 6 mu M with a limit of detection of 6.3 nM, displaying high selectivity toward Ag+ detection in real samples.
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