期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 95, 页码 14311-14314出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc07036b
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资金
- National Natural Science Foundation of China [21702149, 21702153]
- Fundamental Research Funds for the Central Universities [2042018kf0012, 2042018kf0003]
- 1000-Youth Talents Plan
- Open Research Fund of Key Laboratory of the Ministry of Education for Advanced Catalysis Materials
Enantioselective Pd-catalyzed diarylation of unactivated alkenes between arenediazonium salts and arylboronic acids has been developed. This method provides an efficient route to dihydrobenzofurans with all-carbon quaternary centers in good yields with 88-99% ee. This reaction proceeding under mild and open-flask conditions is compatible with a variety of functional groups, including cyano, ketone, ester, amide, bromine and free hydroxyl groups.
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