期刊
ACS APPLIED ENERGY MATERIALS
卷 2, 期 11, 页码 8345-8358出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsaem.9b01850
关键词
MnO@C; morphological/structural evolution; ex-situ characterizations; in-situ EIS; lithium-ion capacitors
资金
- New Century Talent Support Plan of the Ministry of Education of China [2007NCET-07-0723]
- National Natural Science Foundation of China [60936003]
Lithium-ion capacitors (LICs) have captured a lot of attention due to their ability to meld the energy of lithium-ion batteries (LIBs) with the power of supercapacitors (SCs). In this work, high performance LICs were fabricated by using core-shell MnO@C as the anode and trisodium citrate-derived carbon (TSC) as the cathode. Half coin cells with MnO@C anode can deliver a reversible specific capacity of 973.14 mAh g(-1) at 0.25 A g(-1) after 200 cycles. The reversible morphological and structural evolution of MnO@C anode had been unveiled by ex-situ characterizations. Electrode kinetics had also been studied by in situ EIS. Asymmetric LICs with a mass ratio of 1:5 (anode to cathode) have a working voltage of 3.9 V, a maximum energy density of 235 Wh kg(-1) at 120 W kg(-1), and a maximum power density of 25000 W kg(-1) at 61 Wh kg(-1). It can maintain 85.69% of its initial capacity after 10000 cycles. Therefore, the asymmetric MnO@//TSC LIC is demonstrated as a high performance device for energy storage.
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