期刊
CHEMICAL COMMUNICATIONS
卷 55, 期 98, 页码 14769-14772出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc06652g
关键词
-
资金
- National Natural Science Foundation of China [21672049]
- Fundamental Research Funds for the Central Universities of China [PA2019GDPK0056]
An unprecedented gold-catalyzed procedure for the synthesis of polysubstituted 4-quinolones from 1-(2 '-azidoaryl) propynols is described. The reaction undergoes an intramolecular nucleophilic attack of the azide group to the Au-activated triple bonds in a 6-endo-dig manner and subsequent gold-assisted expulsion of N-2 to furnish an alpha-imino gold carbene intermediate, which triggers a 1,2-carbon migration and finally is converted to 2,3-disubstituted 4-quinolone.
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