期刊
JOURNAL OF MATERIALS SCIENCE
卷 53, 期 1, 页码 759-773出版社
SPRINGER
DOI: 10.1007/s10853-017-1537-0
关键词
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资金
- National Natural Science Foundation of China [20976105]
- Shanghai Association for Science and Technology Achievements Transformation Alliance Program [LM201559]
- Shanghai Leading Academic Discipline Project [J51503]
- Shanghai Municipal Education Commission boosting project [15cxy39]
- Science and Technology Commission of Shanghai Municipality Project [14520503200]
- Shanghai Talent Development Funding [201335]
- Shanghai Municipal Education Commission (Plateau Discipline Construction Program)
Poly(m-phenylenediamine)-coated hexagonal Co9S8 was firstly synthesized by the polymerization with self-prepared hexagonal Co(OH)(2) used as cobalt source, and the calcination with sulfur powder providing sulfur source. By adjusting the concentration of m-phenylenediamine in the polymerization process, the coating was achieved with the different coated results, further affecting their supercapacitor behaviors by improving diffusion path for fast electron transfer. The resulting Co9S8/PmPD electrodes demonstrate excellent electrochemical performance with high specific capacitance of 950.1 F g(-1) at a current density of 0.5 a<< g(-1), good rate performance of 81.1% capacitance retention as the current density grows from 0.5 to 20 a<< g(-1), and almost no capacitance loss after 1000 cycles. Moreover, as asymmetric positive electrode material, the Co9S8/PmPD-1 shows high specific capacitance of 115.3 F g(-1) at 0.5 a<< g(-1), outstanding rate performance of 78.2% capacitance retention even increased to 20 a<< g(-1), superior cycle stability of 87.9% capacitance retention after 5000 cycles at 2 a<< g(-1) and largest energy density of 36.0 W h kg(-1) at power density of 374.67 W kg(-1). This novel Co9S8/PmPD composite suggests a bright prospect for supercapacitor applications.
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