期刊
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
卷 7, 期 6, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.jece.2019.103514
关键词
polyacrylonitrile; chitosan; KOH activation; porous carbon; methylene blue adsorption; infrared pyrolysis
A novel procedure of highly-porous polymer-derived carbon preparation was developed. Activated carbon materials (ACMs) based on carbonized chitosan and polyacrylonitrile were prepared via infrared (IR) heating assisted KOH activation. IR radiation provides the significant reduction of the residence time to 2 min at the activation temperature. The chitosan- and polyacrylonitrile-derived ACMs obtained at 800 degrees C are characterized by a microporous structure and have a specific surface area of 2259 and 2438 m(2)g(-1), respectively. The prepared ACMs were proposed as adsorbents for purification of pollutants in water systems. Methylene blue adsorption properties of the chitosan- and polyacrylonitrile-derived ACMs were studied. The prepared samples were best described by Langmuir adsorption model. According to this model, the developed ACMs exhibited the maximum capacity values of 642.1 and 683.8 mg g(-1) for chitosan- and polyacrylonitrile-derived carbons, respectively.
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