Investigations on the Influence of Liquid-Assisted Laser Ablation of NiTi Rotating Target to Improve the Formation Efficiency of Spherical Alloyed NiTi Nanoparticles

In this work, the liquid-assisted laser ablation of NiTi rotating target has been used as a promising technique for generating spherical NiTi alloy nanoparticles with higher formation efficiency. Nd: YAG nanosecond laser with three different laser wavelengths (355, 532 and 1064 nm), three different laser fluences (30, 40 and 50 J/cm(2)) and three different rotational speeds (10 RPM, 20 RPM and 30 RPM) of target has been used to ablate the nitinol (Ni-55%, Ti-45%) target. The influences of different laser parameters (wavelengths and fluences) and different RPMs have been studied on the size, morphology and formation of alloy nanoparticles. It has been observed that the formation efficiency is maximum (39.9 mg/h) for smaller size nanoparticle (similar to 40 nm) at 355 nm wavelength, 50 J/cm(2) fluence and 10 RPM rotational speed. On the other hand, we find that the formation efficiency (10.5 mg/h) is lowest with a bigger size of nanoparticle (similar to 110 nm) at 1064 nm wavelength, 50 J/cm(2) fluence and 30 RPM speed. Therefore, this is a promising technique to synthesize spherical alloy nanoparticles with higher ablation efficiency. Thus, the higher ablation of particles helps to improve the optical absorption of the colloidal solution as optical absorption has a direct relation with the particle concentration. The shape and size of particles were characterized through SEM and DLS analysis whereas the crystallinity was confirmed through TEM and XRD analysis, respectively. Moreover, the elemental analysis was done with the help of XPS and EDS and optical absorption through UV-Vis spectrum analysis.