The design of a multifunctional separator regulating the lithium ion flux for advanced lithium-ion batteries

Herein, we design a controllable approach for preparing multifunctional polybenzimidazole porous membranes with superior fire-resistance, excellent thermo-stability, and high wettability. Specifically, the recyclable imidazole is firstly utilized as the eco-friendly template for micropores formation, which is an interesting finding and has tremendous potential for low-cost industrial production. The unique backbone structure of the as-prepared polybenzimidazole porous membrane endows the separator with superb thermal dimensional stability at 300 degrees C. Most significantly, the inherent flame retardancy of polybenzimidazole can ensure the high security of lithium-ion batteries, and the existence of polar groups of imidazole can regulate the Li+ flux and improve the ionic conductivity of lithium ions. Notably, the cell with a polybenzimidazole porous membrane presents higher capability (131.7 mA h g(-1)) than that of a commercial Celgard membrane (95.4 mA h g(-1)) at higher charge-discharge density (5C), and it can work normally at 120 degrees C. The fascinating comprehensive properties of the polybenzimidazole porous membrane with excellent thermal-stability, satisfying wettability, superb flame retardancy and good electrochemical performance indicate its promising application for high-safety and high-performance lithium-ion batteries.