期刊
DALTON TRANSACTIONS
卷 48, 期 48, 页码 17709-17712出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9dt04147h
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资金
- National Natural Science Foundation of China [21771054, 21571050, 21573056, 21771053]
- Natural Science Foundation of Henan Province [162300410015]
Self-assembly reactions of the Lindqvist-ion salt K7HNb6O19 center dot 13H(2)O, SeO2, and [Cu(2,2'-bipy)](2+) give, depending on different routes, two isopolyoxoniobates based on {Nb-16} and {Nb-20}, respectively, which, as new members of the very limited isopolyoxoniobate family, are observed for the first time. Furthermore, the solution behavior was investigated to determine the stability of the {Nb-16} cluster in water.
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