3.8 Article

Structural and Optoelectron Properties of Hybrid Perovskite Crystals

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SPRINGER
DOI: 10.3103/S8756699019050042

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hybrid perovskites; structural phase transition; photoluminescence

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  1. Ministry of Education and Science of the Russian Federation [RFMEFI62117X0012]
  2. Ministry of Science and Science of the Russian Federation [0306-2019-0015]

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The structure and photoluminescence of CH3NH3PbI3 (lead triiodide methylammonium) synthesized perovskite crystals are investigated in a wide temperature range. As temperature rises to 130-140 K, there is a junction from an orthorhombic to tetragonal crystal lattice with a change in the bandwidth. An increase in the stationary photoluminescence intensity at room temperature under the influence of exciting emission is revealed. A model explaining the observed growth of photoluminescence is proposed.

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