Direct separation of arsenic and antimony oxides by high-temperature filtration with porous FeAl intermetallic

A temperature-controlled selective filtration technology for synchronous removal of arsenic and recovery of antimony from the fume produced from reduction smelting process of lead anode slimes was proposed. The chromium (Cr) alloyed FeAl intermetallic with an asymmetric pore structure was developed as the high-temperature filter material after evaluating its corrosive resistance, structural stability and mechanical properties. The results showed that porous FeAl alloyed with 20 wt.% Cr had a long term stability in a high-temperature sulfide-bearing environment. The separation of arsenic and antimony trioxides was realized principally based on their disparate saturated vapor pressures at specific temperature ranges and the asymmetric membrane of FeAl filter elements with a mean pore size of 1.8 mu m. Pilot-scale filtration tests showed that the direct separation of arsenic and antimony can be achieved by a one-step or two-step filtration process. A higher removal percentage of arsenic can reach 92.24% at the expense of 6 similar to 7% loss of antimony in the two-step filtration process at 500 similar to 550 degrees C and 300 similar to 400 degrees C. The FeAl filters had still good permeable and mechanical properties with 1041 h of uninterrupted service, which indicates the feasibility of this high-temperature filtration technology. (C) 2017 Published by Elsevier B.V.