期刊
JOURNAL OF HAZARDOUS MATERIALS
卷 329, 期 -, 页码 77-83出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jhazmat.2017.01.030
关键词
Double pore structure; Multifunctional adsorption mechanism; Salicylic acid; Adsorption
资金
- National Natural Science Foundation of China [51678225]
Two approaches were used to synthesize two resins with different pore structures. In one way, the-CH(2)C1 groups in macroporous chloromethylated polystyrene resin were transformed to methylene bridges, and achieved a hypercrosslinked resin with plentiful micropores (denoted GQ-06). In the other way, 50% of the-CH2Cl groups in chloromethylated polystyrene resin was used to produce micropores, while the residual 50% of the-CH2Cl groups was reacted with 2-aminopyridine, and prepared another resin with double pore structure of hypercrosslinked resin and macroporous resin (denoted GQ-11). The adsorption of salicylic acid (SA) on GQ-11 was investigated using GQ-06 as the reference adsorbent. The effect of pH on the adsorption of SA on GQ-06 was consistent with the dissociation curve of SA. The maximum adsorption capacity of SA on GQ-11 was observed at the solution pH of 2.64. The greater adsorption rate of SA on GQ-11 than that of GQ-06 was attributed to its double pore structure. The multifunctional adsorption mechanism of anion exchange and hydrophobic interaction resulted in the larger equilibrium capacity of SA on GQ-11 than that of GQ-06. GQ-06 and GQ-11 could be regenerated by absolute alcohol and 80% of alcohol-0.5 mol of sodium hydroxide aqueous solution, respectively. (C) 2017 Elsevier B.V. All rights reserved.
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