期刊
JOURNAL OF HAZARDOUS MATERIALS
卷 338, 期 -, 页码 124-131出版社
ELSEVIER
DOI: 10.1016/j.jhazmat.2017.05.024
关键词
Lithium ion battery; Mechanical separation; Vacuum metallurgy; In situ recovery
资金
- National Natural Science Foundation of China [51534005, 51278293, 51178262]
The large-batch application of lithium ion batteries leads to the mass production of spent batteries. So the enhancement of disposal ability of spent lithium ion batteries is becoming very urgent. This study proposes an integrated process to handle bulk spent lithium manganese (LiMn2O4) batteries to in situ recycle high value-added products without any additives. By mechanical separation, the mixed electrode materials mainly including binder, graphite and LiMn2O4 are firstly obtained from spent batteries. Then, the reaction characteristics for the oxygen-free roasting of mixed electrode materials are analyzed. And the results show that mixed electrode materials can be in situ converted into manganese oxide (MnO) and lithium carbonate (Li2CO3) at 1073 K for 45 min. In this process, the binder is evaporated and decomposed into gaseous products which can be collected to avoid disposal cost. Finally, 91.30% of Li resource as Li2CO3 is leached from roasted powders by water and then high value-added Li2CO3 crystals are further gained by evaporating the filter liquid. The filter residues are burned in air to remove the graphite and the final residues as manganous-manganic oxide (Mn3O4) is obtained. (C) 2017 Elsevier B.V. All rights reserved.
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