期刊
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
卷 791, 期 -, 页码 64-74出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2017.03.005
关键词
Finite element method; Partition coefficient; Facilitated proton transfer; Liquid | liquid interface; Forced hydrodynamic conditions; Magnetic resonance imaging
资金
- Consejo Nacional de Investigaciones Cientificas y Tecnologicas (CONICET) [PIP 00174]
- Secretaria de Ciencia y Tecnologia de la Universidad Nacional de Cordoba (SECyT-UNC) [307-201501-01136-CB]
- Fondo para la Investigation Cientifica y Tecnologica (FONCyT) [PICT-2012-1820]
A novel quantitative methodology to determine the partition coefficients of neutral weak bases is developed. This new electrochemical approach is based on the measurement of the total transferred charge across the oil I water interface under forced hydrodynamic conditions. The complete procedure has been validated by computational simulations and experimental results (Tylosin A). In addition, flow pattern caused inside the electrochemical cell was simulated with computational fluid dynamics using finite element methods and correlated with experimental results obtained by magnetic resonance imaging. (C) 2017 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据