期刊
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
卷 802, 期 -, 页码 22-26出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2017.08.042
关键词
Aqueous batteries; Tunnel oxide; Reaction mechanism; Cycling stability
资金
- Fundamental Research Funds for the Central Universities [2572017CB30]
Tunnel-structured Na(0.5)Mn(0.5)Ti(0.5)O(2)has been synthesized with a simple solid-phase reaction route as highly stable Na-storage cathode for aqueous sodium-ion batteries (SIBs). Combined chracterizations of X-ray diffraction, scanning electron microscope and electrochemical measurements reveal that the material is mainly composed of rod-shaped particles with a diameter of 500 nm and a length of 5 pm. During Na extraction/insertion process, it undergoes a single-phase reaction mechanism in the potential range of 0-1.0 V(vs Ag/AgCl), showing a reversible capacity of 46 mAh g(-1) at a current density of 30 mA g(-1) and an average operating potential of 0.41 V. In particular, excellent cycling performance is achieved owing to the favorable tunnel channel and robust structural framework, with a capacity retention of 95% after 100 cycles. The finding in this study demonstrates application potential of the Na0.5Mn0.5Ti0.5O2 material as cathode for low-cost, long-cycling aqueous SIBs.
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