期刊
CHEMICAL PAPERS
卷 74, 期 5, 页码 1691-1696出版社
SPRINGER INTERNATIONAL PUBLISHING AG
DOI: 10.1007/s11696-019-00993-6
关键词
Lanthanum; Nickel; Electrodeposition; HER; Hydrogen
资金
- National Science Centre, Poland [2016/23/N/ST4/02719]
The overpotential of hydrogen evolution reaction is one of the aspects which results in low efficacy of water electrolysers. There is a constant search for new ways to improve the catalytic activity, especially of nickel-based materials. Addition of lanthanum results in synergism and high activity towards the hydrogen evolution reaction. Due to the application of deep eutectic solvents which are characterized by a wide electrochemical window and good solvent properties for metal ions, it was possible to deposit the lanthanum-nickel alloy coating which was composed of around 40% of La. Hydrogen evolution reaction conducted on this layer resulted in a reduction of overpotential by 129 mV in comparison to pure Ni layer at current density of 1 mA cm(-2). Other kinetic parameters, such as Tafel slope and exchange current density, were also significantly improved. [GRAPHICS] .
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