期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 8, 期 2, 页码 632-638出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ta11023b
关键词
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资金
- Foundation for Innovative Research Groups of the National Natural Science Foundation of China [51621001]
- National Key R&D Program of China [2018YFB1502104]
- Foundation for Research Groups of the Natural Science Foundation of Guangdong Province [2016A030312011]
- National Natural Science Foundation of China [51671087]
- Special Support Plan for National 10000-talents Program
Synthesis of high-performance and low-cost anode electrocatalysts is a central issue in the development of direct hydrazine fuel cells as a viable energy conversion technology. Herein, we report a careful study of nickel nitride as a promising catalyst towards electrooxidation of hydrazine. A hierarchically nanostructured catalyst consisting of tiny Ni3N nanoparticles dispersed on Ni nanosheets is synthesized using a hydrothermal method followed by nitridation treatment. The thus-prepared catalyst exhibits an impressively high activity, good durability and a nearly 100% selectivity towards hydrazine electrooxidation following the 4-electron-pathway, which compares favorably with most DHFC anode catalysts reported to date. Density functional theory calculations were conducted to further understand the outstanding performance of nickel nitride towards hydrazine electrooxidation.
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