期刊
POLYMER CHEMISTRY
卷 11, 期 2, 页码 249-253出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9py00625g
关键词
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资金
- Japan Society for the Promotion of Science (JSPS) through KAKENHI Grant [18K14000, 18K18802]
- Japan Agency for Medical Research and Development (AMED) through The Translational Research program
- Strategic PRomotion for practical application of INnovative medical Technology (TR-SPRINT)
- S-innovation Research Program for the Development of the biofunctional materials for realization of innovative medicine
- Grants-in-Aid for Scientific Research [18K14000, 18K18802] Funding Source: KAKEN
We report on a cost-effective synthesis method for copolymers containing bioinspired phenolic and phosphorylcholine groups in the side chain. Adsorption of the gallol group bearing polymers onto surfaces was compared with reference polymers containing catechol, phenol, phenyl or n-butyl groups. We found that the gallol group was the most effective functional group among those tested to immobilize the low-fouling phospholipid polymer on surfaces. The adlayer exhibited the same degree of low-fouling properties as the commercially available phospholipid polymer (LIPIDURE (R)-PMB), while exhibiting better solvent resistance, especially in water and alcohol. Thus we expect that the reported method may be advantageous in biomedical applications that often involve an alcohol sterilization process.
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