期刊
GREEN CHEMISTRY
卷 22, 期 1, 页码 39-43出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9gc02465d
关键词
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资金
- National Natural Science Foundation of China [21203252]
- Basic Scientific Research of Central Colleges, South-Central University for Nationalities [CZY 19005]
Nitrogen-doped carbon-supported cobalt-molybdenum bimetallic catalysts (abbreviated as Co-Mo/NC) are active for the hydrodeoxygenation of sulfoxides to sulfides under mild conditions (25-80 degrees C and 10 bar H-2), which represents the first example of the use of heterogeneous non-noble metal catalysts for this transformation. MoO3 with Lewis acid sites assists the hydrodeoxygenation of sulfoxides into sulfides by hydrogen over cobalt nanoparticles.
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